The production of sustainable electrochemical energy vectors is one of the main focus areas of our group. We work to design, optimize, and integrate novel electrolysis devices to produce sustainable energy vectors (e.g., hydrogen, synthetic methane, ammonia, and others) to be used as fuels, energy storage, or as sustainable feedstock to the chemical industry.
Electrolysis systems convert electricity and low-value or waste molecules (e.g., water, CO2, nitrogen) into valuable products via a non-spontaneous electrochemical process. High temperature electrolysis (400-800°C) cells and stacks, based on either solid oxides or molten salt electrolytes, as well as polymer electrolyte membrane systems (90-120°C) are poised to be some of the predominant technologies for hydrogen and renewable fuels production via renewable pathways.
We specifically manufacture high temperature solid oxide cells for steam and carbon dioxide reduction, we characterize their electrochemical performance, and evaluate their degradation. We focus on sub-component level design (e.g., electrodes, seals, current collectors) and optimize their integration into a new device of improved performance, demonstrated at lab scale.
Electrolysis technology must reach widespread commercialization and plummet in cost to have a meaningful impact in our race against climate change, other than on reaching our national sustainability targets for H2 production at $1/kg. Therefore, we are focused in providing engineering solutions to scale-up and test electrolysis technologies at the stack and system level.
We investigate solid oxide electrochemical membranes (proton conductors, or oxygen-ion conductors), molten oxide membranes (carbonate-ion conductors, and others), and their composites for gas separation and recovery applications.
In the framework of power-to-gas applications, and blending of hydrogen into the gas grid, we investigate hydrogen electrochemical separation from reducing gases (e.g., natural gas) and compression to pressures relevant to industrial applications (i.e., 10-30 bar) with solid oxide membranes.
Related Projects
Mastropasqua is selected for ARPA-E IGNIITE 2024 Award!
Mastropasqua has been selected by the Advanced Research Project Agency-Energy (ARPA-E) to receive an Inspiring Generations of New Innovators to Impact Technologies in Energy 2024 (IGNIITE 2024) award.
Integrating Nuclear with ZLD Seawater Desalination and Mining
This project performs a feasibility study and cost-benefit analysis of an integrated energy system consisting of a nuclear power plant with zero-liquid-discharge (ZLD) production of power, distillate, and mined commodities. This work paves the way …
HERD Lab Awarded with $10M from DOE Hydrogen and Fuel Cell Technologies Office
The University of Wisconsin-Madison and its partners aim to demonstrate a first-of-a-kind integration of a solid oxide electrolyzer cell (SOEC) with an industrial direct reduction (DR) shaft furnace. SOEC integration with a shaft furnace offers …
[Position Filled] – Position in proton conducting ceramics for electrochemical hydrogen production and separation
Supervisor: Dr. Luca Mastropasqua Contact: luca.mastropasqua@wisc.edu This position has been filled – Please check back soon for more! Summary The HERD Lab at the University of Wisconsin-Madison invites applications for a funded graduate student …
[Position Filled] – Ph.D. position in renewable liquid hydrogen and hydrogen-carriers
Supervisor: Dr. Luca Mastropasqua Contact: luca.mastropasqua@wisc.edu This position has been filled – Please check back soon for more! Research Motivation Road and maritime freight are sources of local emissions (especially diesel-connected PM, NOx and …
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